摘要
Green, biodegradable, and eco-friendly interface materials based on cellulose and its derivatives were prepared for organic solar cells(OSCs). In this work, calcium and two derivatives of cellulose with different carboxy acid groups, denoted as Cellulose-COOH and Cellulose-(COOH)n, were used as cathode interfacial layers of OSCs, and a blend of the low-band-gap semiconducting polymers thieno[3, 4-b]thiophene/benzodithiophene(PTB7)and [6, 6]-phenyl C71-butyric acid methyl ester(PC71BM) was chosen as the photoactive layer. OSCs were fabricated with a configuration of indiumdoped tin oxide(ITO)/poly(3, 4-ethylenedioxythiophene) : polystyrene sulfonate(PEDOT: PSS)/PTB7: PC71BM/Ca or Cellulose-COOH or Cellulose-(COOH)n/Al. As a result, the effect of cellulose-COOH was the best one among them, and the power conversion efficiency(PCE) reached 8.21%for the devices with cathode interfacial layer of Cellulose-COOH, which was better than that of OSCs using calcium as a modifier(PCE=7.95%). The favorable performance is attributed to the reduced work function and improved electron transfer caused by the introduction of carboxy cellulose between the active layer and the electrode. The developed technology shows great potential in accelerating the diversified applications of cellulose and producing cost-effective and eco-friendly interfaces for OSCs.
Green, biodegradable, and eco-friendly interface materials based on cellulose and its derivatives were prepared for organic solar cells（OSCs）. In this work, calcium and two derivatives of cellulose with different carboxy acid groups, denoted as Cellulose-COOH and Cellulose-（COOH）n, were used as cathode interfacial layers of OSCs, and a blend of the low-band-gap semiconducting polymers thieno[3, 4-b]thiophene/benzodithiophene（PTB7）and [6, 6]-phenyl C71-butyric acid methyl ester(PC71BM) was chosen as the photoactive layer. OSCs were fabricated with a configuration of indiumdoped tin oxide（ITO）/poly（3, 4-ethylenedioxythiophene） : polystyrene sulfonate（PEDOT: PSS）/PTB7: PC71BM/Ca or Cellulose-COOH or Cellulose-（COOH）n/Al. As a result, the effect of cellulose-COOH was the best one among them, and the power conversion efficiency（PCE） reached 8.21%for the devices with cathode interfacial layer of Cellulose-COOH, which was better than that of OSCs using calcium as a modifier（PCE=7.95%）. The favorable performance is attributed to the reduced work function and improved electron transfer caused by the introduction of carboxy cellulose between the active layer and the electrode. The developed technology shows great potential in accelerating the diversified applications of cellulose and producing cost-effective and eco-friendly interfaces for OSCs.
基金
financially supported by the National Natural Science Foundation of China(21674123,31700520)
National Natural Science Foundation of Fujian Province(2018J01592)
Project of “100 People Planning in Fujian Province”,New Century Excellent Talents in Fujian Province University(KLa17009A)
International Cooperation Project of Fujian Agriculture and Forestry University(KXGH17003).
