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Synthesis of lathanum or La-B doped KIT-6 mesoporous materials and their application in the catalytic oxidation of styrene 被引量：5

Synthesis of lathanum or La-B doped KIT-6 mesoporous materials and their application in the catalytic oxidation of styrene
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摘要 La-doped and La-B-doped KIT-6 mesoporous materials were prepared by direct hydrothermal synthesis with pH-adjusting method and characterized by X-ray diffractometer(XRD),nitrogen sorption,FT-IR,UV-Vis,X-ray photoelectron spectroscopy(XPS) and ICP-AES.The catalytic performance for the oxidation of styrene by hydrogen peroxide,tert-butyl hydroperoxide or oxygen was investigated.The results showed that the introduction of heteroatoms did not destroy the mesostructure of KIT-6 with cubic Ia3d space group.La or ... La-doped and La-B-doped KIT-6 mesoporous materials were prepared by direct hydrothermal synthesis with pH-adjusting method and characterized by X-ray diffractometer(XRD),nitrogen sorption,FT-IR,UV-Vis,X-ray photoelectron spectroscopy(XPS) and ICP-AES.The catalytic performance for the oxidation of styrene by hydrogen peroxide,tert-butyl hydroperoxide or oxygen was investigated.The results showed that the introduction of heteroatoms did not destroy the mesostructure of KIT-6 with cubic Ia3d space group.La or ...
作者 詹望成 郭杨龙 王艳芹 郭耘 卢冠忠
机构地区 Key Laboratory for Advanced Materials
出处 《Journal of Rare Earths》 SCIE EI CAS CSCD 2010年第3期369-375,共7页 稀土学报（英文版）
基金 supported by the National Basic Research Program of China (2010CB732300) Education Commission of Shanghai Municipality (2008CG35) Science and Technology Commission of Shanghai Municipality (09ZR1408200)
关键词 mesoporous materials oxidation of styrene BENZALDEHYDE styrene oxide rare earths mesoporous materials oxidation of styrene benzaldehyde styrene oxide rare earths
分类号 O621.25 [理学—有机化学]
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参考文献37

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二级参考文献23

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Journal of Rare Earths
2010年 第3期

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