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Preparation,characterization and catalytic oxidation property of CeO_2/Cu^(2+)-attapulgite (ATP) nanocomposites 被引量:8

Preparation,characterization and catalytic oxidation property of CeO_2/Cu^(2+)-attapulgite (ATP) nanocomposites
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摘要 Cerium oxide(CeO2) coated on copper modified attapulgite clay nanocomoposite(CeO2/Cu2+-ATP) was prepared by homogeneous deposition method.The microstructures of the as-prepared CeO2/Cu2+-ATP nanocomposites were characterized by X-ray diffraction(XRD),energy-dispersive spectrometer(EDS) and transmission electron microscopy(TEM).The results indicated that CeO2 particles with average size of about 5 nm were loaded onto the Cu2+-ATP and were widely dispersed.Comparing the catalytic activity of ATP/CeO2 and CeO2/Cu2+-ATP,the catalytic activity was improved when a small quantity of Cu2+ was introduced.The loading amount of CeO2 and reaction temperature had important effects on decolorization ratio of methyl orange(MO).When the loading amount and reaction temperature were 70% and 338 K,respectively,the decolorization ratio of MO reached over 99%,which showed excellent catalytic activity. Cerium oxide(CeO2) coated on copper modified attapulgite clay nanocomoposite(CeO2/Cu2+-ATP) was prepared by homogeneous deposition method.The microstructures of the as-prepared CeO2/Cu2+-ATP nanocomposites were characterized by X-ray diffraction(XRD),energy-dispersive spectrometer(EDS) and transmission electron microscopy(TEM).The results indicated that CeO2 particles with average size of about 5 nm were loaded onto the Cu2+-ATP and were widely dispersed.Comparing the catalytic activity of ATP/CeO2 and CeO2/Cu2+-ATP,the catalytic activity was improved when a small quantity of Cu2+ was introduced.The loading amount of CeO2 and reaction temperature had important effects on decolorization ratio of methyl orange(MO).When the loading amount and reaction temperature were 70% and 338 K,respectively,the decolorization ratio of MO reached over 99%,which showed excellent catalytic activity.
出处 《Journal of Rare Earths》 SCIE EI CAS CSCD 2010年第S1期347-352,共6页 稀土学报(英文版)
基金 Project supported by the National Science Foundation of China (NSFC20771047) Jiangsu Province Key Technology R&D Program (BE2008033) Provincial Science Foundation of Jiangsu (BK2008541)
关键词 ATTAPULGITE cerium dioxide methyl orange catalytic activity rare earths attapulgite cerium dioxide methyl orange catalytic activity rare earths
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