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羟基自由基特性及其化学反应 被引量:35

Characteristics and chemical reaction of hyaroxyl radical
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摘要 对OH·自由基的先进氧化特性进行了研究,并对羟基的化学反应进行了分析.羟基形成时间极短,小于10-12s.OH·一旦形成,会诱发一系列的自由基链反应,氧化分解所有的有机物质、生物体,最终将其降解为CO2、H2O和微量无机盐,不存在有害有毒的残留物.羟基自由基参与的化学反应属于游离基反应,化学反应速度极快.化学反应时间小于1s,生化反应时间1~10s. Hydroxyl radical generation is the mark of technology of advanced oxidation. This paper studied on the characteristics of advanced oxidation,analyzed chemical reaction of hydroxyl. The time of hydroxyl radical formation is very short, less than 10^(-12)s. Once it comes into being, hydroxyl will induce a series of radical chain reaction, oxygenolysis all the matter organic and organism, and its ultimate production is CO_2, H_2O and a little inorganic salt without harmful poisonous residues. The chemical reaction of hydroxyl radical is free radical reaction, whose reaction speed is very high. Its chemical reaction time is less than 1s, and biochemical reaction time is 1~10 s.
出处 《大连海事大学学报》 CAS CSCD 北大核心 2004年第3期62-64,共3页 Journal of Dalian Maritime University
基金 国家自然科学基金重点资助项目(60031001) 国家重大基础研究前期研究专项基金资助项目(2002CCC00900).
关键词 羟基自由基 先进氧化 反应速率常数 hiydroxy radical advanced oxidation, reaction rate constant
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  • 1[1]Susan J Masten,Simon H R Davies.There are more than 40 municipal wastewater treatment plants in the united states that have ozonation facilitie s[J].Environ Sci Technol,1994,28(2):181A-185A.
  • 2[2]Yao C C,Haag W R.Rate constants for direct reaction of ozone with several drinking water contaminates[J].Wat Res,1991,25(4):761-773.
  • 3[3]Haag W R,Yao C C.Rate constants for reaction of hydroxyl r adicals with several drinking water contaminants[J].Environ Sci Technol,1992,2 6(5):1005-1013.
  • 4[4]Olson T M,Barbier P F.Oxidation kinetics of natural organic matt er by sonolysis and ozone[J].Wat Res,1994,28(6):1383-1391.
  • 5[5]Amy G L,Tan L,Davis M K.The effects of ozonation and activated car bon adorption on trihalomethane speciation[J].Wat Res,1991,25(2):191-202.
  • 6[6]Xie Y,Reckhow D A.Identification of trihaloacetaldehydes in ozonated and chlorinated fulvic acid solutions[J].Analyst,1993,118(1):71-72.
  • 7[7]Clasus Hofl,Gerhard Sigl,Oliver Specht,et al.Oxidation degrada tion of AOC COD by different advanced oxidation processes:A comparative study wi th two samples of a pharmaceutical wastewater[J].Wat Sci Technol,1997,35(4):25 7-264.
  • 8[8]Antonio Marco,Santiago Esplugas,Gabriele Saum.How and why combine chemical and biological processes for wastewater treatment[J ].Wat Sci Technol,1997,35(4):321-327.
  • 9[9]Jurg Hoigne.Inter-calibration of OH radical sources and wate r quality parameters[J].Wat Sci Technol,1997,35(1):1-8.
  • 10[10]Vinodgopal K, Peller Tulie,Oksana Markogon,et al.Ultrasonic m iveralization of a reactive textile azo dyes Remazol black B[J].Water Research ,1998,32(12):3646-3650.

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