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低温平衡热液系统中硫同位素演化的Igf_(O_2)-pH图解 被引量:8

LOW TEMPERATURE lgfo_2-PH DIAGRAMS OF SULFUR ISOTOPE EVOLUTION IN EQUILIBRIUM WITH HYDROTHERMAL SYSTEM
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摘要 According to Sakai-Ohmoto's theory regarding the evolution of sulfur isotope in hydrothermal system, by using new data on chemical reaction equilibrium constants,equilibrium isotopic fractionation factors as well as on individual ion activity coeffidents of sulfur species the following diagrams of lgfo2-pH are constructed: a) Mole fraction of aqueous sulfur species (Xt), b) Stable field for some minerals in Fe-S-O system, c) diagram depicting the rate of oxidation-reduction state of aqueous sulfur species(R'), and d) Isotopic composition of sulfur compounds (δSt^34). According to Sakai-Ohmoto 's theory regarding the evolution of sulfur isotope in hydrothermal system, by using new data on chemical reaction equilibrium constants, equilibrium isotopic fractionation factors as well as on individual ion activity coefficients of sulfur species the following diagrams of lgfo2-pH are constructed:a)Mole fraction of aqueous sulfur species (Xi),b)Stable field for Some minerals in Pe-S-O system,c)diagram depicting the rate of oxidation-reduction state of aqueous sulfur species (R'), andd)Isotopic composition of sulfur compounds
出处 《地球化学》 CAS 1982年第3期226-236,共11页 Geochimica
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