对二茂铁基苯甲醛双缩间苯二胺盐酸盐Schiff碱及其过渡金属配合物的合成与表征

Synthesis and Characterization of m-Phenylenediamine Dihydrochloride Bicondensed p-Ferrocenyl Benzaldebyde Schiff Base and Its Transition Metal Complexes

合成了新的二茂铁基苯甲醛双缩间苯二胺盐酸盐Schiff碱[m-C6H4(NCH)2(Cp′FeCp)2]及其过渡金属配合物[m-C6H4(NCH)2(Cp′FeCp)2·MCl2(M=Pd2+,Fe2+,Zn2+)]。其结构经1HNMR,IR和元素分析表征。

A novel o-phenyldiamine bicondensed p-ferrocenyl benzaldehyde Schiff base[m-C 6H 4(NCH) 2(Cp′FeCp) 2] and its transition metal complexes [m-C 6H 4(NCH) 2(Cp′FeCp) 2·MCl 2(M=Pd 2 + , Fe 2 + , Zn 2 + )] were synthesized and characterized by 1H NMR, IR and elemental analysis.