摘要
2,2,3,4,4,4-六氟丁醇是一种重要的含氟有机中间体,可广泛用作溶剂和农药、染料以及含氟特种表面活性剂的制备原料。通过机理分析和对不同引发条件下的自由基加成反应的比较,认为过氧化物引发自由基加成反应制备六氟丁醇具有工业化前景。此外,对六氟丁醇的应用作了简要介绍。
2,2,3,4,4,4-hexafluorobutanol, as an important fluorine-containing intermediate, was widely used in solvents, preparing pesticides and special surfactants containing fluorine. According to the discussion of reaction conditions using different initiations, it was believed that peroxide-initiated free-radical addition reaction was a promising method by mechanism analysis. Thereafter, the application of 2,2,3,4,4,4-hexafluorobutanol was introduced.
出处
《化工新型材料》
CAS
CSCD
北大核心
2006年第1期8-9,23,共3页
New Chemical Materials
关键词
2
2
3
4
4
4-六氟丁醇
调聚反应
自由基加成反应
应用
2,2,3,4,4,4-hexafluorobutanol, telomerization, free-radical addition reaction, application