期刊文献+

生物质热解机理研究进展 被引量:12

The Progress in Biomass Pyrolysis Mechanism Research
下载PDF
导出
摘要 总结了生物质热解动力学模型的研究进展,指出了全局反应动力学模型的不足之处;由此讨论了包含具体热解产物的热解机理反应模型,介绍了近年来热解机理研究的新方法,同时列举了包含新方法的实验例子;最后指出了热解机理研究中存在的关键问题。 The paper summarizes the progress of the study on biomass pyrolysis dynamic model and points out the defects of global reaction dynamic model. And then the pyrolysis mechanism reaction models which include concrete pyrolysis products are disscussed. The paper also introduces some new methods of pyrolysis mechanism besides the experimental examples and at last points out the key items in biomass pyrolysis research.
出处 《工业加热》 CAS 2006年第5期4-8,共5页 Industrial Heating
基金 上海市科学技术委员会的资助(05dz12010)
关键词 生物质 纤维素 半纤维素 木质素 热解 化学动力学 biomass cellulose semicellulose lignin pyrolysis chemical dynamics
  • 相关文献

参考文献29

  • 1马承荣,肖波,杨家宽,李建芬,郭勇,周新平.生物质热解影响因素研究[J].环境技术,2005,23(5):10-12. 被引量:43
  • 2ANTAL M J,VARHEGYI G V.Cellulose Pyrolysis Kinetics:the Current State of Knowledge[J].Ind.Eng.Chem.Res,1995,(34):703-717.
  • 3VARHEGYI G,JAKAB EMMA,Michael Jerry Antal.Is the Broido-Shafizadeh Model for Cellulose Pyrolysis True?[J].Energy&Fuels,1994,(8):1345-1352.
  • 4ALLAN W,BRADBURY,YOSHIO SAKAI,et al.A Kinetic Model for Pyrolysis of Cellulose[J].J.App.Polym.Sci,1979,(23):3271-3280.
  • 5VARHEGYI G,SZABO P,MOK W S L,et al.Kinetics of the Thermal Decomposition of Cellulose in Sealed Vessels at Elevated Pressures:Effects of the Presence of Water on the Reaction Mechanism[J].J.Anal.Appl.Pyrolysis,1993,(26):159-174.
  • 6余春江,骆仲泱,方梦祥,廖燕芬,王树荣,岑可法.一种改进的纤维素热解动力学模型[J].浙江大学学报(工学版),2002,36(5):509-515. 被引量:16
  • 7COLOMBA DI BLASI,MARIO LANZETTA.Intrinsic Kinetics of Isothermal Xylan Degradation in Inert Atmosphere[J].J.Anal.Appl.Pyrolysis,1997 (40):287-303.
  • 8VARHEGYI G,ANTAL M J,SZEKELY·T S,et al.Kinetics of the Thermal Decomposition of Cellulose,Hemicellulose and Sugarcane Bagasse[J].Energy&Fuels,1989,(3):329.
  • 9KOUFOPANOS C A,MASCHIO G,LUCCHESI A.Pyrolysis Kinetics of Wood and Wood Components[J].Can.J.Chem.Eng.,1989,67:75.
  • 10WARD S M,BRASLAW J.Experimental Weight Loss Kinetics of Wood Pyrolysis under Vacuum[J].Combust & Flame,1985,61:261.

二级参考文献67

  • 1崔亚兵,陈晓平,顾利锋.常压及加压条件下生物质热解特性的热重研究[J].锅炉技术,2004,35(4):12-15. 被引量:21
  • 2江淑琴.生物质燃料的燃烧与热解特性[J].太阳能学报,1995,16(1):40-48. 被引量:49
  • 3[1]ZUMDAHL S S. Chemical principles[M]. Lexington: D.C. Heath and Company, 1995.
  • 4[2]GREEN A E, ZANARDI M A, MULLIN J P. Phenomenological models of cellulose pyrolysis[J]. Biomass and Bioenergy, 1997, 13(1-2): 15-24.
  • 5[3]BROIDO A. Kinetics of solid-phase cellulose pyrolysis[A]. Thermal Uses and Properties of Carbonhydrates and Lignin. 172nd National Meeting of the American Chemical Society[C]. San Francisco: Academic Press, 1976. 19-36.
  • 6[4]BRADBURY A W, SAKAI Y, SHAFIZADEH F. Kinetic model for pyrolysis of cellulose[J]. Journal of Applied Polymer Science, 1979, 23(11): 3271-3280.
  • 7[5]ANTAL M J, VARHEGYI G, JAKAB E. Cellulose pyrolysis kinetics: Revisited[J]. Ind Eng Chem Res, 1998, 37(4): 1267-1275.
  • 8[6]GRAHAM R G, BERGOUGNOU M A, FREEL B A. The kinetics if vapor-phase cellulose fast pyrolysis reactions[J]. Biomass and Bioenergy, 1994, 7(1-6): 33-47.
  • 9[7]VARHEGYI G, SZABO P. Kinetics of the thermal decomposition of cellulose under the experimental conditions of thermal analysis: Theoretical extrapolations to higher heating rates[J]. Biomass and Bioenergy, 1994, 7 (1-6): 69-74.
  • 10[8]ANTAL M J, VARHEGYI G. Cellulose pyrolysis kinetics: The current state of knowledge[J]. Ind Eng Chem Res, 1995, 34(3): 703-717.

共引文献298

同被引文献177

引证文献12

二级引证文献61

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部