摘要
探索了用ＴｉＣｌ_４、ＣｕＣｌ_２，·２Ｈ_２Ｏ络合富集页岩油中含氮化合物的最佳条件，建立了一套络合分离页岩油中含氮化合物的实验方法，即依次用ＴｉＣｌ_４络合、ＣｕＣｌ_２·２Ｈ_２Ｏ络合、旋转薄层色谱将样品分成四个组成：未络合分、碱性分、非碱性分Ⅰ、非碱性分Ⅱ，并用ＩＲ法检验了非碱性分Ⅰ和非碱性分Ⅱ的组成。
A systematical method for selective separation of nitrogen compounds from shale oil has been developed. The samples can be divided into four parts (the uncomplexed part,the base part. the non-base partⅠ. the non-base part Ⅱ)by using TiCl_4,complexation.CuCl_2 . 2H_2O complexation and rotating thin layer chromatography (RTLC) in turn. The non-base parts are examined with IR and TLC methods. The non-base partⅠmainly contains carbarzoles, and the non-base part Ⅱ mainly amides.
出处
《石油大学学报（自然科学版）》
CSCD
1996年第A00期77-80,共4页
Journal of the University of Petroleum,China(Edition of Natural Science)
基金
中国石油化工总公司资助
关键词
页岩油
络合
含氮化合物
分离
Shale oil
Separation
Complexation
Nitrogen compounds
