聚醚型聚硅氧烷的研究进展及应用

Research progress and application of polyether/polysiloxane

分子中含有聚醚基团的聚硅氧烷作为重要的功能性有机硅之一,在织物的亲水性抗静电整理、聚氨酯泡沫材料的匀泡、消泡、个人护肤品等方面有广泛应用。简要综述了聚醚型聚硅氧烷的分类、合成方法,对近年来新开发的聚醚基聚硅氧烷在生物医学材料等方面的应用进行了概述,重点介绍了氨基、糖基、聚氨酯、二苯甲酮衍生物、羧基等化学改性以及碱金属络合改性的新型聚醚聚硅氧烷在农药助剂、高能电池电解液等领域的最新研究进展。

Polysiloxanes beating polyether groups （polyether/polysiloxane）, as one of the important functional polysiloxanes, have been widely used for textile hydrophilic antistatic finishing, or as foam stabilizers in production of polyurethane resin, anti-foam agent, personal care and so on. Firstly, the classification, synthesis and applications of polyether/polysiloxane in various industrial processes, especially in some high-tech fields, e.g. biomedical materials, are summarized, then the modified products, such as amino, saccharide, polyurethane, benzophenone derivatives, carboxyl group modified polyether/polysiloxanes as well as the alkali metal chelated polyether/polysiloxanes, and their new developments in pesticide auxiliaries, high-energy battery electrolytes and so on, are introduced in detail.