摘要
用电化学方法测定了异喹啉及其衍生物的缓蚀效率，用ＨＭＯ、ＣＮＤＯ法作量子化学计算表明：随着Ｎ原子负净电荷的减少，缓蚀效率提高；随异喹啉分子的吡啶环负净电荷增大，缓蚀效率也得以提高。根据实验和计算的结果，提出了这类缓蚀剂在ＨＣｌ溶液中以平卧方式吸附于金属表面的模型。
Abstract The structure parameters and corrosion inhibition of isoquinolines were determined by HMO,CNDO and electrochemical methods. The results showed that the inhibition efficiency increases with the decrease of ne\{gat\}ive net charges of N atom and pyridine ring. We \{sug\}gest that the molecules of inhibitors are adsorbed on the surface of Fe electrode in horizontal state.
出处
《材料保护》
CAS
CSCD
北大核心
1998年第3期3-6,共4页
Materials Protection
