期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

一种新的D-π-A型的环金属化有机配体的合成与性质 被引量：1

Synthesis and properties of a new D-π-A type cyclometaled organic ligand
下载PDF
导出
摘要 采用Aldol缩合、Michael加成和无溶剂的Wittig反应等,合成一种新型的D-π-A型的含C^N^N结构的环金属化有机配体:反式-2’-苯基-4-[4’-(N,N-二乙氨基)苯乙烯基]-6’-吡啶基吡啶(6).用傅立叶变换红外光谱、核磁共振、质谱等手段对其进行了结构表征,初步研究了该化合物的紫外-可见光谱、荧光光谱和电化学性质,并通过量子化学计算的方法对光谱进行了合理的解释. Efficent aqueous-phase aldol condensation,Michael addition and solvent-free Wittig reaction were successfully employed to synthesize a new donor-π-acceptor（D-π-A） type C^N^N structure of the cyclometaled organic ligand： trans-2＇-phenyl-4-[4＇-（N,N-diethylamino）styrene-]-6＇-pyridylpyridine（6）.It was characterized by FT-IR,^1H NMR,^13C NMR and MS.Linear optical and electrochemical properties of the novel ligand were invested.Theoretical calculations were consistent with the experimental results.
作者 杜亚军 陆晓斌 徐艳 张海珍 王鹏 杨家祥 田玉鹏 薛照明
机构地区 安徽大学化学化工学院
出处 《安徽大学学报（自然科学版）》 CAS 北大核心 2010年第3期85-90,共6页 Journal of Anhui University(Natural Science Edition)
基金 国家自然科学基金资助项目(50532030 50873001 50703001) 安徽省自然科学基金资助项目(070414188)
关键词 环金属化有机配体 光学性质 电化学性质 量子化学计算 cyclometaled organic ligand optical property electrochemical property quantum chemistry calculation
分类号 O635 [理学—高分子化学]
  • 相关文献

参考文献18

  • 1Freek J M,Pascal J,Meijer E W,et al.About supramolecular assemblies of π-conjugated systems[J].Chem Rev,2005,105(4):1491-1546.
  • 2Bendikov M,Wudl F.Tetrathiafulvalenes,oligoacenenes,and their buckminsterfullerene derivatives:The brick and mortar of organic electronics[J].Chem Rev,2004,104(11):4891-4945.
  • 3Meng H,Sun F P,Marc B G,et al.2,6-bis[2-(4-pentylphenyl)vinyl]anthracene:A stable and high charge mobility organic semiconductor with densely packed crystal structure[J].J Am Chem Soc,2006,128(29):9304-9305.
  • 4Forrest S R.The path to ubiquitous and low-cost organic electronic appliances on plastic[J].Nature,2004,428:911-918.
  • 5Kraft A,Reichert A.Branched non-covalent complexes from carboxylic acids and a tris(tetrahydropyrimidine)base[J].Tetrahedron,1999,55(13):3923-3930.
  • 6Yamaguchi Y,Ochi T,Miyamura S,et al.Rigid molecular architectures that comprise a 1,3,5-trisubstituted benzene core and three oligoaryleneethynylene arms:Light-emitting characteristics and pi-conjugation between the arms[J].J Am Chem Soc,2006,128(14):4504-4505.
  • 7O'Neill M,Kelly S M.Liquid crystals for charge transport,luminescence and photonics[J].Adv Mater,2003,15:1135-1146.
  • 8Shirota Y.Photo and electroactive amorphous molecular materials-molecular design,syntheses,reactions,properties,and applications[J].J Mater Chem,2005,15(1):75-93.
  • 9Strohriegl P,Grazulevicius J V.Charge-transporting molecular glasses[J].Adv Mater,2002,14(20):1439.
  • 10Dimitrakopoulos C D,Malenfant P R L.Organic thin film transistors for large area electronics[J].Adv Mater,2002,14(2):99-117.

同被引文献15

  • 1徐清,王丽,余兴莲,陆炳华,徐伟民.有机电致磷光材料的研究新进展[J].光谱实验室,2006,23(4):772-777. 被引量：7
  • 2Wadman S H, Lutz M, Tooke D M, et al.[J]. Inorg Chem, 2009, 48(5): 1887-1900.
  • 3Hou Q, Zhang Y, Li F Y, et al. [J]. Organometallics, 2005, 24(19): 4509-4518.
  • 4Edia E B, Maxwell J C, David L O, et al. [J]. J porph- yr Phthaloeya, 2002, 6(11): 708-719.
  • 5Gouterman M. [J]. J Mol Spectrosc, 1961, 6: 138- 163.
  • 6Gouterman M. [J]. J Chem Phys, 1960, 33(5): 1523- 1529.
  • 7Cao Y, Parker I D, Heeger J. [J]. Nature, 1999, 397: 414-417.
  • 8LuW, MiBX, CheC M, et al. [J]. J Am Chem Soc, 2004, 126(15): 4958-4971.
  • 9Zuo J L, Yang J X, Wang F Z, et al. [J]. J Photochem Photobiol, A: Chemistry, 2008, 199: 322-329.
  • 10Zhang J P, Xia B H, Jin L,et al. [J]. Theor Chem Acc, 2010, 127: 467-474.

引证文献1

安徽大学学报（自然科学版）
2010年 第3期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部