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Pretreatment of lead anode slime with low silver by vacuum distillation for concentrating silver 被引量:7

Pretreatment of lead anode slime with low silver by vacuum distillation for concentrating silver
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摘要 The feasibility of separation of lead anode slime with low silver by vacuum distillation was analyzed theoretically. The volatilization rates and mass fractions of elements, influenced by distillation temperature, heat preservation time and material thickness, were investigated under laboratory conditions. The experimental results indicate that almost all of lead and bismuth can be separated from silver-contained multicomponent alloy at 1 223 K for 45 min when the chamber pressure maintains at 10-25 Pa. Silver can be easily enriched in the residue and its mass fraction increases from 3.6% to 27.8% when the distillation temperature is between 1 133 K and 1 373 K. Due to the forming ofintermetallic compounds Cu2Sb, Cul0Sb3 and Ag3Sb, the antimony could not be evaporated completely during the vacuum distillation. EDS analysis indicates that the condensate has a columnar crystal structure. The feasibility of separation of lead anode slime with low silver by vacuum distillation was analyzed theoretically.The volatilization rates and mass fractions of elements,influenced by distillation temperature,heat preservation time and material thickness,were investigated under laboratory conditions.The experimental results indicate that almost all of lead and bismuth can be separated from silver-contained multicomponent alloy at 1 223 K for 45 min when the chamber pressure maintains at 10-25 Pa.Silver can be easily enriched in the residue and its mass fraction increases from 3.6% to 27.8% when the distillation temperature is between 1 133 K and 1 373 K.Due to the forming of intermetallic compounds Cu2Sb,Cu10 Sb3 and Ag3 Sb,the antimony could not be evaporated completely during the vacuum distillation.EDS analysis indicates that the condensate has a columnar crystal structure.
出处 《Journal of Central South University》 SCIE EI CAS 2013年第3期615-621,共7页 中南大学学报(英文版)
基金 Project(2010CI009) supported by Science Foundation of Yunnan Province,China Projects(U1202271) supported by the National Natural Science Foundation of China
关键词 Ag-contained multicomponent alloy vacuum distillation SEPARATION intermetallic compounds 铅阳极泥 真空蒸馏 低银 蒸馏浓缩 预处理 实验室条件 宾夕法尼亚州 蒸馏分离
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