摘要
提出了考虑到非广延性时,广延统计力学中的相律已不再适用,推导出了具有非广延性系统的相律形式,以及对广延统计力学中的观念、方法和结论等的几点修正.
This paper deals with a phase rule in form of a non extensive system and with clarification that the thermodynamic limit commonly used in extensive statistical mechanics was no longer applicable when considering non-extensive properties. In addition, amendments have been provided in this paper for some of the ideas and conclusions in extensive statistical mechanics.
出处
《西南师范大学学报(自然科学版)》
CAS
CSCD
北大核心
2013年第11期22-26,共5页
Journal of Southwest China Normal University(Natural Science Edition)
基金
宁夏大学自然科学基金资助项目(ZR1244)
关键词
统计力学
非广延性
相律
热力学极限
广义平衡条件
statistical mechanics
non-extensive property
phase rule
thermodynamic limit
generalized equilibrium condition