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莫来石单相胶前驱体结晶动力学 被引量:1

Crystallization kinetics of mullite from single-phase gel
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摘要 用非等温热分析法研究了莫来石单相胶前驱体的结晶动力学,采用XRD、TEM和27 Al-NMR分析了前驱体向莫来石转化的微观结构变化。结果表明,前驱体在950℃开始形成莫来石晶体,结晶过程为以Avrami-Erofeev的随机形核和随后生长机制,动力学三因子:活化能Ea=1 086.34kJ/mol,指前因子A=9.33×1042s-1,机理函数的微分表达式f(α)=n(1-α)[-ln(1-α)],其中n=3.37。结晶动力学为非均匀形核过程,形核速率I随时间t而下降;980℃左右主要以形核控制为主,1 000℃左右则以核生长控制为主,晶粒的长大为扩散控制长大机制。 The crystallization kinetics of mullite from single-phase gel were studied using a non-isothermal ther-mal analysis method.The microstructure changes were investigated by X-ray power diffraction (XRD),trans-mission electron microscopy (TEM)and 27 Al nuclear magnetic resonance (NMR)spectroscopy.The results show mullite crystallization begins from 950 ℃.The crystallization process confroms to random nuclei produc-tion and the following unclei growth model of n-dimension Avrami-Erofeev.The activation energy Ea and the pre-exponential factor A of mullite crystallization are 1 086.34 kJ/mol and 9.33×1042 s-1,respectively.The differential expression of the corresponding mechanism function was f (α)=n(1-α)[-ln(1-α)] n-1 n ,n=3.37.The nucleation rates are non-uniform which decrease with the time t in crystallization process.Nuclea-tion was the dominant controlling step at about 980 ℃.Nucleation-growth becomes more predominant at about 1 000 ℃.The rates of the grain growth are controlled by diffusion.
出处 《功能材料》 EI CAS CSCD 北大核心 2013年第24期3571-3575,共5页 Journal of Functional Materials
基金 中央高校基本科研业务费专项资金资助项目(2011-1a-031) 国家自然科学基金A3前瞻计划资助项目(51161140399)
关键词 莫来石单相胶 结晶动力学 非等温热分析 速率控制步骤 mullite single-phase gel crystallization kinetics non-isothermal thermal analysis the rate controllingstep
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