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全氧冠醚聚硅氧烷毛细管气相色谱固定液的色谱性能和机理研究 被引量:6

Studies on Chromatographic Characteristics and Mechanism of theSide-chain Oxygen Crown Ethers Polysiloxane as StationaryPhases for Capillary Gas Chromatography
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摘要 本文合成了2种新型聚硅氧烷侧链全氧冠醚(十一烷氧甲基18-冠-6和十一烷氧甲基15-冠-5),并将其涂渍、交联在未经处理的弹性石英毛细管柱上,其柱效较高,使用温度范围较宽,热稳定性和选择性较好.研究了固定液对样品的分离机理. Two new kinds of crown ether, n-undecyloxymethyl-18-crown-6(or 15-crown-5) side-chain polysiloxane were prepared and coated on capillary column. Their chromatographic characteristics including column efficiency, allowable operating temperature range, thermal stability, polarity and selectivity were studied, and their separation mechanism was discussed.
机构地区 武汉大学化学系
出处 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 1991年第2期173-176,共4页 Chemical Journal of Chinese Universities
基金 国家自然科学基金
关键词 冠醚 聚硅氧烷 气相色谱 固定液 Stationary phase, Crown ether, Polysiloxane, Quartz glass capillary, Gas chromatogra-Phy
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参考文献2

  • 1Jin Yonghao,J Chromatogr,1989年,469卷,153页
  • 2李如松,色谱,1986年,4卷,304页

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