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EB-PVD热障涂层高温氧化过程中的显微结构和相分析 被引量:10

STUDIES OF MICROSTRUCTURE AND PHASE OF EB-PVD TBCs EXPOSED TO ELEVATED TEMPERATURES
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摘要 采用磁控溅射方法在镍基单晶高温合金基体上沉积NiCrAlY粘结层 ,电子束物理气相沉积方法 (EB -PVD)沉积陶瓷层 (7mass%Y2 O3 -ZrO2 ) .用X -射线衍射 (XRD)、扫描电镜 (SEM )等研究了EB -PVD热障涂层热循环过程中的相变 ,同时观察了样品的形貌变化 .结果表明 ,EB -PVD方法沉积的陶瓷层 ,其柱状晶粒簇拥成团 ,表面比较致密 ,然而晶粒簇间存在间隙 ,允许柱状晶横向伸缩 ,使基体能在相对大的范围内自由膨胀 .经高温氧化后 ,陶瓷层表面变得疏松 ,柱状晶粒簇间距增大 ,随着热循环的继续进行 ,相邻较大的间隙互相连接而形成微裂纹 ,并逐渐横向及纵向扩展 .循环氧化比恒温氧化更易于产生显微裂纹 .10 5 0℃热循环过程中 ,ZrO2 正方相的c/a轴比值逐渐增加 ,Y2 O3 含量逐渐减少 ,非平衡正方相逐渐分解成平衡正方相和立方相 .循环 30 0次后 ,观察到少量从平衡正方相转变而来的单斜相 . A NiCrAlY bond coat had been deposited on a Ni-base single crystal superalloy by magnetron sputtering,and then a top coat (7 mass%Y 2O 3-ZrO 2) had been deposited by electron beam-physical vapor deposition (EB-PVD).The phase transformation of ceramic top coat was investigated and the surface morphology change of the samples was observed.It was found that the ZrO 2-7 mass% Y 2O 3 ceramic top coat deposited by EB-PVD showed columnar grains which formed dense clusters and the surface was relatively dense.However there were gaps or holes among grain clusters,which allowed the lateral expansion and contraction of the ceramic columnar grains and allowed free expansion of the substrate over a relatively large range.After exposure to elevated temperatures,the gaps among columnar grain clusters became larger.The relatively large gaps interconnected into one another and formed microcracks.With thermal cycling going on,the microcracks extended across and through the top coat.Also the Y 2O 3 content in nonequilibrium tetragonal phase decreased gradually,and the nonequilibrium tetragonal phase decomposed to equilibrium tetragonal and cubic phases.After 300 thermal cycles at 1050℃,small amount of monoclinic phase was formed from the decomposition of the tetragonal phases.
出处 《中国腐蚀与防护学报》 CAS CSCD 2002年第2期105-110,共6页 Journal of Chinese Society For Corrosion and Protection
关键词 高温氧化 电子束物理气相沉积 热障涂层 显微裂纹 相变 electron beam physical vapor deposition,thermal barrier coating (TBC),microcrack,phase transformation
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