Oxidative Debenzylation and Acetylation of Hexabenzylhexaazaisowutzitane

Oxidative Debenzylation and Acetylation of Hexabenzylhexaazaisowutzitane

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摘要 The oxidative reactivity of hexabenzylhexaazaisowutzitane(HBIW)under different conditions was studied. It was found that the N-benzyl groups were found to form benzoyl group after oxidation. They might also be first debenzylated and then acetylated by potassium permanganate in acetic anhydride/DMF. The oxidative reactivity of hexabenzylhexaazaisowutzitane(HBIW)under different conditions was studied. It was found that the N-benzyl groups were found to form benzoyl group after oxidation. They might also be first debenzylated and then acetylated by potassium permanganate in acetic anhydride/DMF.

作者 PANG Si-ping, Yü Yong-zhong, ZHAO Xin-qi (School of Chemical Engineering and Material Science, Beijing Institute of Technology, Beijing 100081, China)

出处《含能材料》 EI CAS CSCD 2002年第2期66-68,共3页 Chinese Journal of Energetic Materials

关键词氧化乙酰化炸药 HBIW 苯甲基 N-benzyl oxidation debenzylation acetylation

分类号 O626 [理学—有机化学]

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含能材料

2002年第2期

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Oxidative Debenzylation and Acetylation of Hexabenzylhexaazaisowutzitane

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