摘要
In this study, we synthesized molybdenum disulfide/polyaniline(MoS2/PANI) nanocomposite via in situ polymerization of aniline in the presence of thin-layered MoS2. The as-prepared MoS2/PANI nanocomposite obtained an improved electrochemical performance due to the physisorption interaction between aromatic aniline and the basal plane of MoS2. Furthermore, we constructed a new kind of electrochemical sensor based on MoS2/PANI nanocomposite for the detection of chloramphenicol, which showed an excellent performance. The sensor has a high sensitivity and wide detection range from 1 ×10^(-7)mol/L to 1×10^(-4)mol/L, with a low detection limit of 6.9 × 10^(-8)mol/L.
In this study, we synthesized molybdenum disulfide/polyaniline(MoS2/PANI) nanocomposite via in situ polymerization of aniline in the presence of thin-layered MoS2. The as-prepared MoS2/PANI nanocomposite obtained an improved electrochemical performance due to the physisorption interaction between aromatic aniline and the basal plane of MoS2. Furthermore, we constructed a new kind of electrochemical sensor based on MoS2/PANI nanocomposite for the detection of chloramphenicol, which showed an excellent performance. The sensor has a high sensitivity and wide detection range from 1 ×10^(-7)mol/L to 1×10^(-4)mol/L, with a low detection limit of 6.9 × 10^(-8)mol/L.
基金
supported by the National Natural Science Foundation of China (Nos. 21275084 and 41476083)
Doctoral Foundation of the Ministry of Education of China (No. 20113719130001)
Scientific and Technical Development Project of Qingdao (No. 12-1-4-3-(23)-jch)
Outstanding Adult-Young Scientific Research Encouraging Foundation of Shandong Province (No. BS2012CL013)