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Study on the rheology of coal-oil slurries during heating at high pressure 被引量:4

Study on the rheology of coal-oil slurries during heating at high pressure
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摘要 Using the self-developed viscosity measuring device, the viscosity variations of coal-oil slurries with temperature increasing during coal-oil co-processing were studied. The results show that the viscosity of coal-oil slurries prepared by different kinds of oil varies differently during heating. The viscosity of the coal-oil slurry prepared by the catalytic cracking slurry (FCC) generally decreases during heating. However, the viscosity of the coal-oil slurry prepared by the high-temperature coal tar (CT) will peak at 338 ℃ during heating. The differences in viscosity variations of coal-oil slurries are analyzed. In addition to the temperature, the properties of the solvents and coal are the main influencing factors. Because the used coal contains a large number of polar functional groups, the swelling behavior of the coal in polar solvent (CT) is stronger than that in non-polar solvent (FCC). The swelling effect of the coal can result in the appearance of the viscosity peak. Therefore, before 100 ~C, the solvent molecules entering into the coal pores is the main influencing factor of coal-oil slurries viscosity variations. After 100 ℃, the increasing of particle size of coal particles is the main influencing factor of coal-oil slurries viscosity variations.
作者 Bingfeng Yan
出处 《International Journal of Coal Science & Technology》 EI 2017年第3期274-280,共7页 国际煤炭科学技术学报(英文)
关键词 Coal-oil slurry · Rheology· Swelling · High temperature and pressure 加热过程 煤浆 流变特性 粘度测量装置 非极性溶剂 粘度变化 高压 催化裂化油浆
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