摘要
To fully analyze emission characteristics of volatile organic compounds( VOCs) from automobile coating industry in Chongqing City,related enterprises in the city were investigated in detail. The results show that the emission of VOCs from the automobile industry in Chongqing City was approximately 20 000 t in 2012,and the contribution rate of automobile coating was 83%. Most VOCs discharged from automobile coating industry were mainly from the use of coatings,diluents,curing agents and other materials containing VOCs. During the process of automobile coating,VOCs were mainly produced during the processes of spraying and drying. Besides,VOCs are partly produced during the processes of mixing paint,gluing,waxing,and repairing. The major ingredients of VOCs discharged during the process of automobile coating were methylbenzene,dimethylbenzene,trimethylbenzene,cumene,ethyl acetate,butyl alcohol,n-butyl alcohol,isobutyl alcohol,formaldehyde,butanone,acetone,cyclohexanone,and methyl ethyl ketone. Besides,the ingredients of naphtha and aromatic hydrocarbon in VOCs need to be determined. The maximum ozone formation potential( OFP) of the above pollutants by the typical enterprises was 900-1 300 mg/m^3. The production of secondary organic aerosol( SOA) was 3 636-11 073 t/a,which didn't include the contribution of aldehydes,ketones,ethers and esters to SOA. This research could provide scientific reference for the establishment of emission standard,control technology and management methods of VOCs from automobile coating industry that accord with economic and social development in Chongqing City.
To fully analyze emission characteristics of volatile organic compounds( VOCs) from automobile coating industry in Chongqing City,related enterprises in the city were investigated in detail. The results show that the emission of VOCs from the automobile industry in Chongqing City was approximately 20 000 t in 2012,and the contribution rate of automobile coating was 83%. Most VOCs discharged from automobile coating industry were mainly from the use of coatings,diluents,curing agents and other materials containing VOCs. During the process of automobile coating,VOCs were mainly produced during the processes of spraying and drying. Besides,VOCs are partly produced during the processes of mixing paint,gluing,waxing,and repairing. The major ingredients of VOCs discharged during the process of automobile coating were methylbenzene,dimethylbenzene,trimethylbenzene,cumene,ethyl acetate,butyl alcohol,n-butyl alcohol,isobutyl alcohol,formaldehyde,butanone,acetone,cyclohexanone,and methyl ethyl ketone. Besides,the ingredients of naphtha and aromatic hydrocarbon in VOCs need to be determined. The maximum ozone formation potential( OFP) of the above pollutants by the typical enterprises was 900-1 300 mg/m^3. The production of secondary organic aerosol( SOA) was 3 636-11 073 t/a,which didn't include the contribution of aldehydes,ketones,ethers and esters to SOA. This research could provide scientific reference for the establishment of emission standard,control technology and management methods of VOCs from automobile coating industry that accord with economic and social development in Chongqing City.
