摘要
Contents 1.Introduction 8562.C—O Activation via the in-situ Formed Intermediate 8562.1.C—C bond formation 8562.2.C—X bond formation 8573.C—O Activation via Dearomatization-Condensation-Rearomatization Process 8573.1.Heterogeneous catalyzed C—O cleavage of phenols,dearomatization-condensation-rearomatization process in a gas phase 8573.2.Dearomatization-condensation-rearomatization process in a liquid phase 8574.Deoxygenation 8585.Direct C—O Activation of Phenol Salts 8596.Direct C—O Activation of Phenol 8607.Conclusions and Perspective 8601.Introduction Transition-metal-catalyzed cross-coupling reactions of aryl electrophiles with organic or organometallic reagents emerged as one of the most powerful tools for constructing aromatic compounds.[1]In the early days,the most popular electrophiles werearyl halides because of their high reactivity and availability.
基金
This work was sponsored by the"973"Project from the MOST of China(2015CB856600)(Z.Shi)
Shanghai Gaofeng&Gaoyuan Project for University Academic Program Development(F.Liu).
