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Investigation on Preparation and Fluorescence Properties of Oxy-Fluoride Glass Co-Doped with Er^(3+) and Yb^(3+) 被引量:3

Investigation on Preparation and Fluorescence Properties of Oxy-Fluoride Glass Co-Doped with Er^(3+) and Yb^(3+)
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摘要 The glass sample based on the composition of 45PbF_2-45GeO_2-10WO_3 co-doped with Yb^(3+)/Er^(3+) was prepared by the fusion method in two steps: melted at 950 ℃ for 20~25 min then annealed at 380 ℃ for 4 h. Through the V-prism it is found that the refractive index of host glass and the sample are 1.517 and 1.65 respectively. The transmittance was observed by using the ultraviolet-visible-infrared spectrometer in the wavelength range from 0.35 to 2.5μm. The transmittance of the host glass is beyond 73%. That of the sample is beyond 50% and there are characteristic absorption peaks of rare-earth ions. The emission spectrum was measured by using the Hitachi F-4500 fluorescent spectrometer pumped by 980 nm semiconductor laser. There are a strong emission peak at 530 nm and a weak peak at 650 nm. The glass sample based on the composition of 45PbF_2-45GeO_2-10WO_3 co-doped with Yb^(3+)/Er^(3+) was prepared by the fusion method in two steps: melted at 950 ℃ for 20~25 min then annealed at 380 ℃ for 4 h. Through the V-prism it is found that the refractive index of host glass and the sample are 1.517 and 1.65 respectively. The transmittance was observed by using the ultraviolet-visible-infrared spectrometer in the wavelength range from 0.35 to 2.5μm. The transmittance of the host glass is beyond 73%. That of the sample is beyond 50% and there are characteristic absorption peaks of rare-earth ions. The emission spectrum was measured by using the Hitachi F-4500 fluorescent spectrometer pumped by 980 nm semiconductor laser. There are a strong emission peak at 530 nm and a weak peak at 650 nm.
出处 《Journal of Rare Earths》 SCIE EI CAS CSCD 2004年第4期458-460,共3页 稀土学报(英文版)
基金 ProjectsupportedbyKeyLaboratoryofRareEarthChemistryandPhysics ChangchunInstituteofAppliedChemistry ChineseAcademyofSciences
关键词 oxy-fluoride glass Yb^(3+)/Er^(3+) fusion method spectrum rare earths oxy-fluoride glass Yb^(3+)/Er^(3+) fusion method spectrum rare earths
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