摘要
海水中的溶解无机碳(DIC)可占海水中总碳的95%以上,其准确测量是研究海洋碳循环的基础。目前测量DIC所使用的仪器较为昂贵、复杂,不适于外海调查。实验设计了一套密封的气提吸收装置,并通过大量的实验建立了一种简便、快速的DIC现场测定方法,即取大约100~150mL海水,加10%H3PO4将其中的CO2释放出来,用0.1mol/LNaOH进行二级吸收,以酚酞和溴甲酚绿甲基红混合指示剂指示终点,用HCl标准溶液滴定所吸收的CO2,计算DIC含量。经检验该方法具有较高的精密度和准确度,相对标准偏差为076%。用该方法测定了2003年6月取自胶州湾的水样,结果表明胶州湾内表层水DIC平均为2066μmol/L,底层水为2075μmol/L;湾外表层水平均为1949μmol/L。
Dissolved inorganic carbon (DIC) account for more than 95% of total carbon in seawater, so it is necessary to make reliable and precise measurements of DIC to study marine carbon cycling. In order to establish a simple and speed method, an airproof device of gas extraction-absorption was designed. Finally a simple method was developed for the determination of DIC in seawater through a large mount of experiments. The determination procedure is as follows: 100 similar to 150 mL seawater was put into conical flask, then add 10% H3PO4, the DIC in seawater sample was dissolved to form CO2 gas and carried by pure N-2, then the CO2 gas was absorbed by two grades 0.1 mol/L NaOH solution. Finally the absorbed solution was titrated by HCl standard solution of 0.01000 mol/L with the end points detected with the indicator phenolphthalein and bromocresol green-methyl red mixture. The precision and accuracy of the method were satisfied. This method was used to analyse seawater samples from Jiaozhou bay in June, 2003. The result shows that the average DIC in surface seawater is 2066 mumol/L, DIC in bottom seawater is 2075 mumol/L inside bay, but the average DIC in surface seawater is 1949 mumol/L, DIC in bottom seawater is 2147 mumol/L outside bay.
出处
《分析化学》
SCIE
EI
CAS
CSCD
北大核心
2004年第12期1689-1692,共4页
Chinese Journal of Analytical Chemistry
基金
青岛市科技将才专项计划
中国科学院"百人计划"
中国科学院创新重大项目(No.KZCX1SW0108
KZCX3SW214)
国家杰出青年科学基金(No.49925614)资助课题