摘要
It is difficult to treat 2-amino-thiazoline-4-carboxylic acid （ATC） waste liquid effectively at present for its characteristics of high chemical oxygen demand （COD）, high salinity and low biodegradability. In order to solve this problem, this paper presents several kinds of physical-chemical treatment unit techniques, including acid separation, catalytic oxidation and coagulation. First of all, acid separation was adopted to precipitate relevant organics at isoelectric point. When the temperature and pH value of acid separation were controlled at about 5 ℃ and 2.2 respectively, the COD removal rate could reach 27.600. Secondly, oxidation was used to break chemical constitution of refractory organics. The optimal reaction parameters of catalytic oxidation should be 20 ℃, pH adjusted to 5.0 and [Fe2+] 300 mg/L. Then with 500 H2O2 added and after one-hour reaction, the COD removal rate could achieve about 5200. Finally, coagulation was adopted to remove a portion of refractory organics, and 1500 polymeric molysite flocculant was the best for the coagulation, and the COD removal rate could reach about 1500. Therefore, the proposed feasible process of physical-chemical pretreatment for ATC waste liquid could have about 7000 COD removed in total.
It is difficult to treat 2-amino-thiazoline-4-carboxylic acid (ATC) waste liquid effectively at present for its characteristics of high chemical oxygen demand (COD), high salinity and low biodegradability. In order to solve this problem, this paper presents several kinds of physical-chemical treatment unit techniques, including acid separation, catalytic oxidation and coagulation. First of all, acid separation was adopted to precipitate relevant organics at isoelectric point. When the temperature and pH value of acid separation were controlled at about 5 ℃ and 2.2 respectively, the COD removal rate could reach 27.6~0_0. Secondly, oxidation was used to break chemical constitution of refractory organics. The optimal reaction parameters of catalytic oxidation should be 20 ℃, pH adjusted to 5.0 and [Fe^(2+)] 300 mg/L. Then with 5~0_0 H_2O_2 added and after one-hour reaction, the COD removal rate could achieve about 52~0_0. Finally, coagulation was adopted to remove a portion of refractory organics, and 15~0_0 polymeric molysite flocculant was the best for the coagulation, and the COD removal rate could reach about 15~0_0. Therefore, the proposed feasible process of physical-chemical pretreatment for ATC waste liquid could have about 70~0_0 COD removed in total.
基金
SupportedbyTianjinYouthScienceFoundation(No.973705411).
