A New Kind of Void Soap-free P(MMA-EA-MAA) Latex Particles
A New Kind of Void Soap-free P(MMA-EA-MAA) Latex Particles
摘要
Soap-free P(MMA-EA-MAA) particles with narrow size distribution were synthesized by seeded emulsion polymerization of methyl methacrylate (MMA), ethyl acrylate (EA) and methacrylic acid (MAA), and large voids inside the particles were generated by alkali posttreatment in the presence of 2-butanone. Results indicated that the size of void and the particle volume were related with the amount of 2-butanone. The generation mechanism of voids was proposed.
基金
the National 863 Project of China(grant No.2001AA242041)for financial support
参考文献10
-
1M.S. Rosa, F. Jacqueline, J. Polym. Sci., Part A: Polym. Chem., 1997, 35, 1605.
-
2M. Schwartz, H. Kossmann, European Coating Journal, 1998, 3, 134.
-
3H.C. Li, X. D. Li, L. Yang, Image Technology, 2002, 4, 29.
-
4J.W. Vanderhoff, Polym. Mater. Sci. Eng., 1994, 64, 345.
-
5M. Okubo, In: Division of Polymer Chemistry Ed., International Conference on Synthesis and Properties of Polymer Emulsion, Japan: Kob, 1993, p. 118.
-
6M. Okubo, K. Ichikawa, ColloidPolym. Sci., 1994, 272, 933.
-
7X.Z. Kong, C.Y. Kan, H.H. Li, et al., Polym. Adv. Technol., 1997, 8, 627.
-
8C.Y. Kan, M.H. Liu, Q. Yuan, et al., Acta Polymerica Sinica, 1999, 6, 687.
-
9Y. Kan, J. Sun, Q. Yuan, et al., Polymer Materials Science and Engineering, 2000, 16, 58.
-
10M. Okubo, A. Ito, T. Kanenobu, Colloid Polym. Sci., 1996, 274, 801.
-
1王敏.低成本耐擦洗内外墙涂料的研制与施工[J].北京建材,1998(3):12-13.
-
2刘宏,向寓华,蒲德兴.涂料用苯丙乳液合成工艺条件的优化[J].电镀与涂饰,2007,26(8):33-35. 被引量：7
-
3李子东.瓦克公司推出醋酸乙烯类聚合乳液新品[J].粘接,2009(2):80-80.
-
4卢素敏,王洪卫.苯丙乳液聚合粒度影响因素的研究[J].化工时刊,2004,18(12):47-49. 被引量：6
-
5张静,杨永兵,朱志开,李锦春,陈强.含氟丙烯酸酯核壳乳液的制备与性能研究[J].涂料工业,2014,44(3):33-38. 被引量：2
-
6赵全生,王敏杰.核壳聚合乳胶涂料的研究[J].涂料技术,1997(4):5-8.
-
7行业动态[J].环球聚氨酯,2009(12):32-33.
-
8罗门哈斯无皂聚合乳液用于水性木器涂料[J].中国涂料,2008,23(5).
-
9刘浏,戴震,王萃萃,许戈文.涂料用环氧改性水性聚氨酯[J].涂料工业,2010,40(12):28-32. 被引量：11
-
10罗门哈斯无皂聚合乳液用于水性木器涂料[J].新型建筑材料,2008(5):87-87.
