摘要
La2O3 and SrO-doped CaO-MgO-Nb2O3-TiO2 system ceramics were prepared by solid-state ceramic technique.The microstructure and microwave dielectric properties of CaO-MgO-Nb2O5-TiO2-La2O3 cermics can be adjusted by varying the amount of La^3＋ or Sr^2＋ ions respectively.The replacement of Ca^2＋ by La^3＋ at A-site of the ceramics increases the quality factor Q value（ at 7.6GHz）as well as the temperature coefficient of resonant frequency τf and decreases the dielectric constant εr and the substitution of Sr^2＋ at A-site in this ceramics system exhibits opposite characteristics.The microwave properties of La^3＋,Sr^2＋-doped CaO-MgO-Nb2O5-TiO2 system ceramics depend on the degree of octahedral distortion inside materials.
La2O3 and SrO-doped CaO-MgO-Nb2O3-TiO2 system ceramics were prepared by solid-state ceramic technique.The microstructure and microwave dielectric properties of CaO-MgO-Nb2O5-TiO2-La2O3 cermics can be adjusted by varying the amount of La^3＋ or Sr^2＋ ions respectively.The replacement of Ca^2＋ by La^3＋ at A-site of the ceramics increases the quality factor Q value（ at 7.6GHz）as well as the temperature coefficient of resonant frequency τf and decreases the dielectric constant εr and the substitution of Sr^2＋ at A-site in this ceramics system exhibits opposite characteristics.The microwave properties of La^3＋,Sr^2＋-doped CaO-MgO-Nb2O5-TiO2 system ceramics depend on the degree of octahedral distortion inside materials.
基金
FundedbytheNationalNaturalScienceFoundationofChina(50272044)
