摘要
A new aromatic asymmetrical ether diamine, 1,4-bis（3＇,4’-diaminophenoxy）benzene 3 was synthesized in three steps, using hydroquinone as starting material. A new aromatic polyimide containing asymmetrical diaryl ether segments was prepared from the resulting diamine with 4,4＇-oxydiphthalic anhydride （ODPA） via a conventional two-step thermal or chemical imidization method. The resulting polyimide exhibits high thermal resistance, excellent solubility, film-forming capability, high mechanical strength and modulus.
A new aromatic asymmetrical ether diamine, 1,4-bis（3＇,4’-diaminophenoxy）benzene 3 was synthesized in three steps, using hydroquinone as starting material. A new aromatic polyimide containing asymmetrical diaryl ether segments was prepared from the resulting diamine with 4,4＇-oxydiphthalic anhydride （ODPA） via a conventional two-step thermal or chemical imidization method. The resulting polyimide exhibits high thermal resistance, excellent solubility, film-forming capability, high mechanical strength and modulus.
