Preparation and Electrochemical Performances of Nickel Metal Hydride Batteries with High Specific Volume Capacity

Cylindrical nickel metal hydride （Ni-MH） battery with high specific volume capacity was prepared by using the oxyhydroxide Ni（OH）2 and AB5 type hydrogen storage alloy and adjusting the designing parameters of positive and negative electrodes. The oxyhydroxide Ni（OH）2 was synthesized by oxidizing spherical β-Ni（OH）2 with chemical method. The X-ray diffraction （XRD） patterns and the Fourier transform infrared （PT-IR） spectra indicated that 7-NiOOH was formed on the oxyhydroxide Ni（OH）2 powders, and some H2O molecules were inserted into their crystal lattice spacing. The battery capacity could not be improved when the oxyhydroxide Ni（OH）2 sample was directly used as the positive active materials. However, based on the conductance and residual capacity of the oxyhydroxide Ni（OH）2 powders, AA size Ni-MH battery with 2560 mA.h capacity and 407 W·h·L^-1 specific volume energy at 0.2C was obtained by using the commercial spherical β-Ni（OH）2 and AB5-type hydrogen-storage alloy powders as the active materials when 10% mass amount of the oxyhydroxide Ni（OH）2 with 2.50 valence was added to the positive active materials and subsequently the battery designing parameters were adjusted as well. The as-prepared battery showed 70% initial capacity after 80 cycles at 0.5C. The possibility for adjusting the capacity ratio of positive and negative electrodes from 1 ： 1.35 to 1 ： 1.22 was demonstrated preliminarily. It is considered the as-prepared battery can meet the requirement of some special portable electrical instruments.

有高特定的体积能力的圆柱的镍金属氢化物(Ni-MH ) 电池被使用 oxyhydroxide Ni 准备(哦) 2 并且 AB5 类型氢存储合金并且调整积极、否定的电极的设计参数。oxyhydroxide Ni (哦) 2 被氧化综合有化学方法的球形的 -Ni(OH)2。X 光检查衍射(XRD ) 模式和 Fourier 转变红外线(英尺红外) 系列显示 -NiOOH 在 oxyhydroxide Ni 上被形成(哦) 2 粉末，和一些 H2O 分子被插入到他们的晶体格子间距。当时，电池能力不能被改进 oxyhydroxide Ni (哦) 2 样品直接被用作积极活跃材料。然而，基于传导力和 oxyhydroxide Ni 的剩余能力(哦) 2 搽粉，与 2560 妈一起的 AA 尺寸 Ni-MH 电池？