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Baeyer-Villiger oxidation of cyclic ketones utilizing potassium peroxydisulfate(K_2S_2O_8) or sodium perborate(NaBO_3) in acidic media 被引量:8

Baeyer-Villiger oxidation of cyclic ketones utilizing potassium peroxydisulfate(K_2S_2O_8) or sodium perborate(NaBO_3) in acidic media
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摘要 The efficient, green, facile, mild and straightforward conversion procedure for the oxidation of cyclic ketones to lactones at room temperature utilizing potassium peroxydisulfate (K2S2O8) in acidic media is satisfactory to high yields without using traditional chlorinated solvents is reported. This oxidative reagent is cheap and friendly environmental procedure for industrial purposes than use of organic peracids. The efficient, green, facile, mild and straightforward conversion procedure for the oxidation of cyclic ketones to lactones at room temperature utilizing potassium peroxydisulfate (K2S2O8) in acidic media is satisfactory to high yields without using traditional chlorinated solvents is reported. This oxidative reagent is cheap and friendly environmental procedure for industrial purposes than use of organic peracids.
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 2009年第12期1400-1404,共5页 中国化学快报(英文版)
基金 support and purchase of Hewlett-Packard 6890 GC-Hewlett-Packard 5973N MSD instrument.
关键词 Baeyer-Villiger oxidation Cyclic ketones Potassium peroxydisulfate (K2S208) Acidic media Sodium perborate (NaBO3) Baeyer-Villiger oxidation Cyclic ketones Potassium peroxydisulfate (K2S208) Acidic media Sodium perborate (NaBO3)
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