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天门冬氨酸催化1,1,1,3,3,3-六甲基二硅氮烷硅烷化羟基为三甲基硅醚(英文) 被引量:1

Protection of Hydroxyl Groups as a Trimethylsilyl Ether by 1,1,1,3,3,3-Hexamethyldisilazane Promoted by Aspartic Acid as an Efficient Organocatalyst
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摘要 A wide variety of alcohols and phenols were protected as trimethylsilyl ethers using 1,1,1,3,3,3-hexamethyl disilazane catalyzed by aspartic acid as a non-toxic,metal-free,and green organocatalyst at room temperature in acetonitrile under mild and heterogeneous conditions.The procedure is operationally simple and the silylated product was obtained in high yield and purity. A wide variety of alcohols and phenols were protected as trimethylsilyl ethers using 1,1,1,3,3,3-hexamethyl disilazane catalyzed by aspartic acid as a non-toxic,metal-free,and green organocatalyst at room temperature in acetonitrile under mild and heterogeneous conditions.The procedure is operationally simple and the silylated product was obtained in high yield and purity.
出处 《催化学报》 SCIE EI CAS CSCD 北大核心 2011年第4期595-598,共4页
基金 supported by the research facilities of Ilam University,Ilam,Iran
关键词 ALCOHOL PHENOL 1 1 1 3 3 3-hexamethyldisilazane TRIMETHYLSILYLATION protection alcohol phenol 1 1 1 3 3 3-hexamethyldisilazane trimethylsilylation protection
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