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Solid-Liquid Equilibria of D-Glucose,D-Fructose and Sucrose in the Mixture of Ethanol and Water from 273.2 K to 293.2 K 被引量:5

Solid-Liquid Equilibria of D-Glucose,D-Fructose and Sucrose in the Mixture of Ethanol and Water from 273.2 K to 293.2 K
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摘要 Experimental data on the solubility of D-glucose,D-fructose and sucrose in the mixed solvents com-posed of water and ethanol from 273.2 to 293.2 K were determined.The solubility of D-glucose,D-fructose and sucrose decreased as the ethanol content increased in the mixed solvent.The solubility of D-glucose,D-fructose and sucrose decreased with decreasing equilibrium temperature.The modified UNIQUAC model,S-UNIFAC model and mS-UNIFAC model were applied to predict the solid-liquid equilibria.The prediction results were compared and discussed.Better prediction accuracy was generated using the modified UNIQUAC model. D 葡萄糖的溶解度上的试验性的数据, D 果糖并且在从 273.2 ~ 293.2 K 由水和乙醇组成的混合溶剂的蔗糖被决定。D 葡萄糖的溶解度, D 果糖并且蔗糖作为内容在混合溶剂增加了的乙醇减少了。D 葡萄糖的溶解度, D 果糖并且蔗糖与减少的平衡温度减少了。修改 UNIQUAC 模型, S-UNIFAC 模型和 mS-UNIFAC 模型被使用预言稳固液体的 equilibria。预言结果被比较并且讨论。更好的预言精确性用修改 UNIQUAC 模型被产生。
出处 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2011年第2期217-222,共6页 中国化学工程学报(英文版)
基金 Supported by the National Science and Technology Major Project (2009ZX09313-036) the China Postdoctoral Science Foundation (20090461360) the Zhejiang Provincial Education Department Projects (Y200907556)
关键词 GLUCOSE FRUCTOSE SUCROSE ETHANOL solid-liquid equilibria 乙醇含量 固液平衡 葡萄糖 蔗糖 果糖 UNIQUAC模型 UNIFAC模型 混合物
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