摘要
Submicron-sized peanut-shaped poly(methyl methacrylate)/polystyrene (PMMA/PS) particles were successfully synthesized by seeded soap-free emulsion polymerization of styrene on the spherical crosslinked PMMA seed particles. The obtained peanut- shaped particles showed a novel internal morphology: PS phase formed one domain which linked to the other domain having PMMA core encased by PS shell.
Submicron-sized peanut-shaped poly(methyl methacrylate)/polystyrene (PMMA/PS) particles were successfully synthesized by seeded soap-free emulsion polymerization of styrene on the spherical crosslinked PMMA seed particles. The obtained peanut- shaped particles showed a novel internal morphology: PS phase formed one domain which linked to the other domain having PMMA core encased by PS shell.
基金
supported by National Natural Science Foundation of China(No.50943028)
Scientific Research Foundation for the Returned Overseas Chinese Scholars,State Education Ministry