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Controllable synthesis of titania/reduced graphite oxide nanocomposites with various titania phase compositions and their photocatalytic performance 被引量:1

Controllable synthesis of titania/reduced graphite oxide nanocomposites with various titania phase compositions and their photocatalytic performance
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摘要 A facile method is presented for preparing TiO2/reduced graphite oxide (RGO) nanocomposites with phase-controlled TiO2 nanoparticles via redox reaction between the reductive titanium (III) precursor and graphite oxide (GO), and a series of TiO2/RGO composites with various TiO2 phase compositions were obtained. In all the titania/RGO composites, the TiO2 nanoparticles were uniformly distributed on the surface of the RGO. The TiO2 consisted of anatase phase particles in the form of square-plates with edges less than 10 nm and the rutile phase nanorods in diameters less than 10 nm. The performances of the as-prepared TiO2/RGO composites were investigated on catalytically degrading phenol under visible light irradiation. The TiO2/RGO composites can effectively degrade phenol under visible light irradiation, and the phase composition of TiO2 in the composites significantly influences the activities of these catalysts. A facile method is presented for preparing TiO2 /reduced graphite oxide(RGO) nanocomposites with phase-controlled TiO2 nanoparticles via redox reaction between the reductive titanium(Ⅲ) precursor and graphite oxide(GO),and a series of TiO2 /RGO composites with various TiO2 phase compositions were obtained.In all the titania/RGO composites,the TiO2 nanoparticles were uniformly distributed on the surface of the RGO.The TiO2 consisted of anatase phase particles in the form of square-plates with edges less than 10 nm and the rutile phase nanorods in diameters less than 10 nm.The performances of the as-prepared TiO2 /RGO composites were investigated on catalytically degrading phenol under visible light irradiation.The TiO2 /RGO composites can effectively degrade phenol under visible light irradiation,and the phase composition of TiO2 in the composites significantly influences the activities of these catalysts.
出处 《Science China Chemistry》 SCIE EI CAS 2012年第7期1294-1302,共9页 中国科学(化学英文版)
基金 supported by the National Natural Science Foundation of China (20903105,21073202) the Ministry of Science and Technology of China (973 project,2009CB930802) the Chinese Academy of Sciences (KJCX2.YW.H16)
关键词 TITANIA phase control reduced graphite oxide COMPOSITE 纳米复合材料 二氧化钛 光催化性能 氧化石墨 相组成 纳米TiO2 氧化还原反应 可见光照射
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