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Magnetic and specific heat studies of the frustrated Er_2Mn_2O_7 compound

Magnetic and specific heat studies of the frustrated Er_2Mn_2O_7 compound
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摘要 A new ErzMn207 compound was synthesized by the ceramic method and its crystal structure was characterized LJsing powder X-ray diffraction (XRD) and observed by scanning electron microscopy (SEM). The magnetic properties were investigated using a BS2 magnetometer and the heat capacity was studied using a quantum design (PPMS). The structural study revealed that this compound was monophasic and crystallized in the monoclinic system with the P2/M space group. Magnetization measurements were carried out in the temperature range of 1.8-200 K under an applied magnetic field of 0.05 T. A crossover from a room temperature para- magnetic phase to an antiferromagnetic one at low temperature was detected from the magnetic study. The magnetic susceptibility, in the paramagnetic region above 40 K, was found to present a simple Curie-Weiss type behavior. From the specific heat (G,) measurements in magnetic fields up to 5 T, we noted the presence of a wide peak characteristic of a second order magneto-structural transition. A new ErzMn207 compound was synthesized by the ceramic method and its crystal structure was characterized LJsing powder X-ray diffraction (XRD) and observed by scanning electron microscopy (SEM). The magnetic properties were investigated using a BS2 magnetometer and the heat capacity was studied using a quantum design (PPMS). The structural study revealed that this compound was monophasic and crystallized in the monoclinic system with the P2/M space group. Magnetization measurements were carried out in the temperature range of 1.8-200 K under an applied magnetic field of 0.05 T. A crossover from a room temperature para- magnetic phase to an antiferromagnetic one at low temperature was detected from the magnetic study. The magnetic susceptibility, in the paramagnetic region above 40 K, was found to present a simple Curie-Weiss type behavior. From the specific heat (G,) measurements in magnetic fields up to 5 T, we noted the presence of a wide peak characteristic of a second order magneto-structural transition.
出处 《Journal of Rare Earths》 SCIE EI CAS CSCD 2013年第1期54-59,共6页 稀土学报(英文版)
基金 Project supported by Tunisian Ministry of Higher Education and Scientific Research The Portuguese Ministry of Higher Education and Scientific Research(Portuguese Agency for Science and Technology FCT)Project Tunisian-Portuguese20/TP/09 The French Ministry of Higher Education and Scientific Research(project CMCU10G1117)
关键词 magnetic frustration magnetic phase transition specific heat rare earths magnetic frustration magnetic phase transition specific heat rare earths
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