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Degradation of Nitrobenzene-Containing Wastewater with O_3 and H_2O_2 by High Gravity Technology 被引量:17

Degradation of Nitrobenzene-Containing Wastewater with O_3 and H_2O_2 by High Gravity Technology
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摘要 Nitrobenzene-containing industrial wastewater was degraded in the presence of ozone coupled with H2O2 by high gravity technology. The effect of high gravity factor, H2O2 concentration, pH value, liquid flow-rate, and reaction time on the efficiency for removal of nitrobenzene was investigated. The experimental results show that the high gravity technology enhances the ozone utilization efficiency with O3/H202 showing synergistic effect. The degradation efficiency in terms of the COD removal rate and nitrobenzene removal rate reached 45.8% and 50.4%, respectively, under the following reaction conditions, viz.: a high gravity factor of 66.54, a pH value of 9, a H2O2/O3 molar ratio of 1:1, a liquid flow rate of 140 L/h, an ozone concentration of 40 rag/L, a H2O2 multiple dosing mode of 6 mL/h, and a reaction time of 4 h. Compared with the performance of conventional stirred aeration mixers, the high gravity technology could increase the COD and nitrobenzene removal rate related with the nitrobenzene-containing wastewater by 22.9% and 23.3%, respectively. Nitrobenzene-containing industrial wastewater was degraded in the presence of ozonecoupled with H2O2 by high gravity technology. The effect of high gravity factor, H2O2 concentration, pH value, liquid flow-rate, and reaction time on the efficiency for removal of nitrobenzene was investigated. The experimental results show that the high gravity technology enhances the ozone utilization efficiency with O3 /H2O2 showing synergistic effect. The degradation efficiency in terms of the COD removal rate and nitrobenzene removal rate reached 45.8% and 50.4%, respectively, under the following reaction conditions, viz.: a high gravity factor of 66.54, a pH value of 9, a H2O2 /O3 molar ratio of 1:1, a liquid flow rate of 140L/h, an ozone concentration of 40mg/L, a H2O2 multiple dosing mode of 6mL/h, and a reaction time of 4h. Compared with the performance of conventional stirred aeration mixers, the high gravity technology could increase the COD and nitrobenzene removal rate related with the nitrobenzene-containing wastewater by 22.9% and 23.3%, respectively.
出处 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS 2013年第1期85-94,共10页 中国炼油与石油化工(英文版)
基金 financially supported by the National Natural Science Foundation of China(21206153) Science and Technology Development Program Fund of Taiyuan City(120164053)
关键词 nitrobenzene containing wastewater rotating packed bed OZONE H2O2 free radicals 硝基苯废水 重力技术 降解效率 H2O2 COD去除率 O3 液体流速 反应时间
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