三聚体二苯基锗氧化合物的合成及晶体结构研究(英文)

Synthesis and Crystal Structure of Containing Germanium and Oxygen Atoms Heterocyclic Tripolymer(Ph_2GeO)_3

研究了用二苯基二氯化锗的水解反应 ,得到了三聚体二苯基锗氧化合物 ,用 X-射线晶体衍射确定了结构 .配合物为单斜晶体 ,空间群 P2 1/c.晶体学数据 :a=1 .0 0 1 8( 2 ) ,b=1 .862 4 ( 4 ) ,c=1 .770 9( 4 ) nm,β=93.49( 3) 0 ,V=330 4 .0 ( 1 1 ) nm3,Z=4,Dcal.=1 .464mg/m3,F( 0 0 0 ) =1 464,R1=0 .0 4 38,w R2 =0 .0

The tripolymer compound (Ph 2GeO) 3 has been synthesized with a novel method and characterized by means of X\|ray single crystal diffraction.The structure features of the compound are described.