八甲基环四硅氧烷与氨取代基有机硅单体的共聚动力学I聚合机理与动力学模型

Copolymerization Kinetics of Octamethylcyclotetrasiloxane and Amio-silicone Monomer Ⅰ Polymerization Mechanism and Kinetic Model

基于质量作用原理 ,实验研究了八甲基环四硅氧烷与氨取代基有机硅单体的共聚反应动力学规律。提出了共聚机理 。

The copolymerization kinetics rules of octamethylcyclotetrasiloxane with amino silicone monomer were experimentally investigated in this paper. The rusults showed that the copolymerization mechanism was intervenient between chain and step reaction .According to this mechanism, the polymerization kinetics model was proposed based on the classic conservation of mass and the probably element reaction ,while the solution of this model was given.