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频哪醇联硼酸酯B_2pin_2在偶联反应中的应用 被引量：2

Application of Bis( pinacolato ) diboron(B_2pin_2) in Coupling Reaction
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摘要 标题化合物是一类非常有用的硼试剂。综述了B2pin2在不同过渡金属催化下与不同有机底物生成不同的有机硼中间体,并且通过硼中间体转化为各类有机化合物。同时列举了一些重要的硼中间体化合物(如烯硼、烯丙基硼、1,3-丁二烯硼化合物)的合成。 Bis（pinacolato） diboron as a useful reagent has a broad application on organic synthesis. In this work ,various reactions of B2pin2 and different organic substrate with the catalysis of different transitional metals to give useful boryl intermediate and their further conversion into other organic compounds is reviewed. Meanwhile,the preparation of some useful boryl compound as alke- nylborate,allylbornate and 2-boryl 1,3-butadiene is elucidated with examples.
作者 楼鑫 张祯琦
机构地区 中国科学技术大学化学与材料科学学院 滁州学院材料与化学工程学院
出处 《化学试剂》 CAS 北大核心 2015年第6期511-514,共4页 Chemical Reagents
基金 安徽省教育厅高校自然科学基金资助项目(KJ2014A181)
关键词 B2pin2 Miyaura硼化反应 偶联反应 B2 pin2 Miyaura borylation coupling reaction
分类号 O627.31 [理学—有机化学]
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化学试剂
2015年 第6期

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