摘要
An air-stable supported Cu(I) catalyst, Cu I@PS-Phen, was designed and synthesized. Cu I@PS-Phen can efficiently catalyze the click polymerization of diynes a and diazides b to produce soluble and thermally stable polytriazoles with high molecular weights(Mw up to 30800), and low copper residue content(down to 190 ppm) in high yields(up to 94.2%) under mild reaction conditions without the exclusion of oxygen.
An air-stable supported Cu（I） catalyst, CuI@PS-Phen, was designed and synthesized. CuI@PS-Phen can efficiently catalyze the click polymerization of diynes a and diazides b to produce soluble and thermally stable polytriazoles with high molecular weights （Mw up to 30800）, and low copper residue content （down to 190 ppm） in high yields （up to 94.2%） under mild reaction conditions without the exclusion of oxygen.
基金
supported by the National Natural Science Foundation of China(21490571,21222402,21174120)
the Key Project of the Ministry of Science and Technology of China(2013CB834702)
the Research Grants Council of Hong Kong(604711,602212,604913)
Anjun Qin and Benzhong Tang thank the support from Guangdong Innovative Research Team Program(201101C0105067115)
