期刊文献+

Pt/FeSnO(OH)_5: A Novel Supported Pt Catalyst for Catalytic Oxidation of Benzene

Pt/FeSnO(OH)_5: A Novel Supported Pt Catalyst for Catalytic Oxidation of Benzene
下载PDF
导出
摘要 Pt/FeSnO(OH)_5 was synthesized as a novel catalyst for VOCs oxidation. Compared with Pt/γ-Al_2O_3 during catalytic oxidation of benzene, Pt/Fe Sn O(OH)5 showed better catalytic activity. After characterization of the catalysts by XRD, SEM, TEM, EDS, XPS, BET, TGA and DTA, we found most Pt could be reduced to metallic state when the hydroxyl catalyst was used as supporter, and the metallic Pt in Pt/Fe Sn O(OH)5 was more active than the oxidized Pt in Pt/γ-Al_2O_3 in catalytic oxidation of VOCs. Pt/FeSnO(OH)_5 shows both good catalytic activity and high stability, which may be a promising catalyst. This study may also be helpful for the design and fabrication of new catalysts. Pt/FeSnO(OH)_5 was synthesized as a novel catalyst for VOCs oxidation. Compared with Pt/γ-Al_2O_3 during catalytic oxidation of benzene, Pt/Fe Sn O(OH)5 showed better catalytic activity. After characterization of the catalysts by XRD, SEM, TEM, EDS, XPS, BET, TGA and DTA, we found most Pt could be reduced to metallic state when the hydroxyl catalyst was used as supporter, and the metallic Pt in Pt/Fe Sn O(OH)5 was more active than the oxidized Pt in Pt/γ-Al_2O_3 in catalytic oxidation of VOCs. Pt/FeSnO(OH)_5 shows both good catalytic activity and high stability, which may be a promising catalyst. This study may also be helpful for the design and fabrication of new catalysts.
出处 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2016年第6期889-902,共14页 结构化学(英文)
基金 supported by the National Natural Science Foundation of China(No.51102047,51472050) the Natural Science Foundation of Fujian Province(No.2013J05027) the Fujian Province Education-science Project for Middle-aged and Young Teachers(No.JA13050)
关键词 FeSnO(OH)5 supported Pt catalyst catalytic oxidation of benzene FeSnO(OH)5 supported Pt catalyst catalytic oxidation of benzene
  • 相关文献

参考文献27

  • 1Li, Z. H.; Yang, K.; Liu, G.; Deng, G. F.; Li, J. Q.; Li, G.; Yue, R. L.; Yang, J.; Chen, Y. F. Effect of reduction treatment on structural properties of TiO2 supported Pt nanoparticles and their catalytic activity for benzene oxidation. Catal. Left. 2014, 144, 1080-1087.
  • 2Shim, W. G.; Lee, J. W.; Kim, S. C. Analysis of catalytic oxidation of aromatic hydrocarbons over supported palladium catalyst with different pretreatments based on heterogeneous adsorption properties. Appl. Catal. B: Environ. 2008, 84, 133-141.
  • 3Wu, J. C. S; Lin, Z. A.; Pan, J. W.; Rei, M H A novel boron nitride supported Pt catalyst for VOC incineration. Appl. Catal. A: Gen. 2001, 219, 117-124.
  • 4Girandon, J. M; Elhachimi, A.~ Leclercq, G. Catalytic oxidation of chlorobenzene over Pd/perovskites. Appl. Catal. B: Environ. 2008, 84, 251-261.
  • 5Diehl, F.; Barbier, J.; Duprez, D.; Guibard, I.; Mabilon, G Catalytic oxidation of heavy hydrocarbons over Pt/A12Os: influence of the structure of the molecule on its reactivity. Appl. Catal. B: Environ. 2010, 95, 217-227.
  • 6Lin, C. A.: Wu, J. C. S.; Pan, J. W.: Yeh, C. T. Characterization of boron-nitride-supponed Pt catalysts for the deep oxidation of benzene. ~ Catal. 2002, 210, 39-45.
  • 7Esctmd6n, L. S.; Ord6flez~ S.', Vega, A; Diez, F. Oxidation of methane over palladium catalysts effect of the support. Chemosphere 2005, 5g, 9-17.
  • 8Silviya, T.; Georgi, K.: Krasimir, T.; Yuri, K.~ Vladislav, K. K. Particle size and support effects on the complete benzene oxidation by Co and Co-Pt catalysts. Z Mater. $ci. 2007, 42, 3315-3320.
  • 9Miller, J. B.; Malatpure, M. Pd catalysts for total oxidation of methane support effects. AppI. Catal. A: Gen. 2015, 495, 54-62.
  • 10Corro, G.; Cano, C.; Fierro, J. L. G. A study of Pt-Pd-AI203 catalysts for methane oxidation resistant to deactivation by sulfur poisoning. 3. 114o1. Catal. A: Chem. 2010, 315, 35-42.

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部