摘要
Amino 4,6 dimethoxypyrimidine(AMP) was synthesized using benzyltriethyl ammonium chloride(BTEA) as a catalyst in yield of 87 5%. A solid complex Co(AMP) 2Cl 2 was obtained by refluxing AMP with CoCl 2 in ethanol. The composition of the complex was determined by chemical and elemental analyses. The structure of the complex and sp 3 d 2 of the hybridization type of Co 2+ were estimated by IR, XPS and 1H NMR.
Amino 4,6 dimethoxypyrimidine(AMP) was synthesized using benzyltriethyl ammonium chloride(BTEA) as a catalyst in yield of 87 5%. A solid complex Co(AMP) 2Cl 2 was obtained by refluxing AMP with CoCl 2 in ethanol. The composition of the complex was determined by chemical and elemental analyses. The structure of the complex and sp 3 d 2 of the hybridization type of Co 2+ were estimated by IR, XPS and 1H NMR.
出处
《应用化学》
CAS
CSCD
北大核心
2002年第9期917-918,共2页
Chinese Journal of Applied Chemistry
基金
国家自然科学基金 (2 0 1710 3 6)
陕西省教育厅专项基金 (H F0 13 0 4)
西北大学科研基金 (0 0 NW43 )资助项目
