植物纤维基3D打印材料的荧光增亮研究

The Study on Fluorescence Brightening of Plant Fiber-based 3D Printing Materials

以植物纤维为代表的生物材料是地球上极为丰富的天然资源,在自然条件下可完全生物降解,3D打印制造与其相结合将推动我们过渡到环境友好型和循环型制造模式。植物纤维材料原料来源色泽品质不一致,难以获得纯色的标准原料,我们则利用荧光标记技术改善植物纤维材料在3D打印应用中的这一问题。本文以三聚氯氰和4,4-二氨基二苯乙烯-2,2'-二磺酸(DSD酸)为分子骨架,以苯胺和吗啉为取代基合成几种三嗪基氨基二苯乙烯型活性荧光标记分子,再通过其与植物纤维材料进行活性标记反应,将荧光分子键合标记于植物纤维材料结构之上,用以改善材料的光谱色度性能。活性荧光标记分子的吸收峰主波长在太阳光的近紫外波长范围内,其荧光发射峰的波长在蓝紫光波长范围内。耐水洗实验结果显示其耐水洗牢度大大超过非活性荧光分子,说明活性基团确实可以提高荧荧光标记分子的耐水洗牢度。

Biomaterials represented by plant fibers are abundant natural resources on the earth.The combination of 3D printing and manufacturing will promote our transition to environmentally friendly and circular manufacturing mode.We use fluorescence labeling technology to improve the chromaticity problem of plant fiber materials in 3D printing applications. A number of triazine-stilbene type fluorescent reactive molecules are prepared and labelled onto the plant fibers by chemical reactions.The L* values are measured and indicate the brightening effect.The washing fastness are studied as well.