摘要
Ten known flavonoid C-glycosides identified as 2′′-O-β-D-glucopyranosyl isovitexin(1),spinosin(2),6′′′-acetyl spinosin(3),6′′′-p-hydroxycinnamoyl-2′′O-β-D-glucopyranosyl isovitexin(4),6′′′-p-hydroxy-cinnamoyl spinosin(5),6′′′-(E)-feruloyl O-β-Dglucopyranosyl isovitexin(6),isospinosin(7),isovitexin(8),swertisin(9),swertiajaponin(10)were purified from the seeds of Hovenia dulcis Thunb.Their structures were confirmed by spectroscopic data analysis and comparison with previous literature.All compounds were obtained from H.dulcis for the first time.
本文对北枳椇种子的化学成分进行研究,从中分离得到10个黄酮碳苷类成分,通过波谱解析、理化常数及比对文献数据资料进行结构鉴定,分别为2′′-O-β-D-glucopyranosyl isovitexin(1),spinosin(2),6′′′-acetyl spinosin(3),6′′′-phydroxycinnamoyl-2′′O-β-D-glucopyranosyl isovitexin(4),6′′′-p-hydroxy-cinnamoyl spinosin(5),6′′′-(E)-feruloyl O-β-Dglucopyranosyl isovitexin(6),isospinosin(7),isovitexin(8),swertisin(9),swertiajaponin(10)。所有化合物均首次从该植物中分离得到。
基金
National Natural Science Foundation of China(Grant Nos.81703379 and U1801287)
Key-Area Research and Development Program of Guangdong Province(Grant No.2020B1111110007)
Science and Technology Planning Project of Guangdong Province(Grant No.2018B020207008)
Key Laboratory Program of Guangzhou(Grant 201902010082)
the Specific Research Fund for TCM Science and Technology of Guangdong Provincial Hospital of Chinese Medicine(Grant Nos.YN2016QJ05 and YN2015MS03)
Key Project of High-level University Construction of Guangzhou University of Chinese Medicine(Grant No.XK2018019)。