同质异构Al-Cu-Mg系混晶粉末冶金制备新方法

New powder metallurgy preparation method of homogeneous and isomeric Al-Cu-Mg mixed crystal materials

为突破传统同质粉末材料均以颗粒尺寸细化作为改性的单一途径禁锢,提出同质异构思想,即通过低能球磨将不同粒径的AA2024合金粉末按照一定比例混合,经热压烧结制备混晶坯料。研究结果表明,传统单一粒径粉末烧结后晶粒形貌趋向于不规则多边形状,而不同粒径粉末混合烧结后晶粒形貌为小颗粒包覆大颗粒的结构形式;与前者相比,当粗粉占比为20%(质量分数)时,抗拉强度增加了38.8%;当粗粉占比为50%时,伸长率提高了14%。粉末混合后的烧结样品呈沿晶断裂和穿晶断裂的混合断裂机制,第二相对位错的钉扎效应更加明显,因此,合金性能得到显著提高。此研究工作为高性能同质异构混晶材料的制备提供了一种新思路。

A new idea of homogeneity isomerism is proposed in this work to break through the single restriction that traditional homogeneous powder metallurgy materials take refining particles as the only modification method. AA2024 alloy powders of different diameters are mixed in a certain proportion through low-energy ball milling, and then a kind of mixed crystal material is successfully fabricated by hot pressing sintering. The results show that the grain morphology of the traditional sample sintered with single-diameter particles tends to become irregular polygon shape, while the grain morphology of the mixed crystal materials forms a special structure in which larger grains are coated with smaller grains. Compared with the former, when the proportion of coarse particles is 20%(mass fraction), the tensile strength increases by 38.8%;when the proportion of coarse particles is 50%, the elongation increases by 14%. The mixed crystal material exhibits a mixed fracture mechanism of intergranular fracture and transgranular fracture, and the pinning effect of the second phase on the dislocation is more obvious, so the properties of the alloy are improved significantly. The above research provides a new idea for the preparation of high-performance homogeneous isomeric mixed crystal materials.