摘要
金属有机框架(MOFs)材料由于高比表面积、多孔性、化学可调性及丰富的活性位点等功能特性,在多相催化领域得到广泛应用。针对MOFs基复合材料在催化合成生物柴油中的应用,综述了MILs基、ZIFs基、UiO基、MOFs衍生物基等四类复合材料的制备、特性及催化行为等。对MOFs基复合材料面临的机遇和挑战进行了展望。
Metal-organic frameworks(MOFs)materials have been widely used in thefield of multiphase catalysis due to their high specific surface area,porosity,chemical tunability,and abundant active sites.This review focuses on the application of MOFs-based composite materials for catalytic synthesis of biodiesel,and summarizes the design,preparation,physicochemical properties,and catalytic activity of four types of MOFs-based composite materials,including MILs-based,ZIFs-based,UiO-based,MOFs derivatives-based composites.The challenges and prospects of MOFs-based composite materials are also discussed.
作者
张秋云
李伟华
赵永婷
张玉涛
ZHANG Qiuyun;LI Weihua;ZHAO Yongting;ZHANG Yutao(Key Laboratory of Agricultural Resources and Environment in High Education Institute of Guizhou Province,School of Chemistry and Chemical Engineering,Anshun University,Anshun 561000,China)
出处
《石油化工》
CAS
CSCD
北大核心
2024年第2期240-250,共11页
Petrochemical Technology
基金
国家自然科学基金项目(22262001)
贵州省高等学校多孔材料与绿色催化创新团队项目(黔教技[2023]086号)
贵州省高等学校农业资源与环境研究重点实验室项目(黔教技[2023]025)。
关键词
金属有机框架
复合材料
催化剂
生物柴油
酯化
酯交换
metal-organic framework
composite material
catalyst
biodiesel
esterification
transesterification