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Enhancing corrosion resistance of plasma electrolytic oxidation coatings on AM50 Mg alloy by inhibitor containing Ba(NO_(3))_(2) solutions

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摘要 To enhance the long-term corrosion resistance of the plasma electrolytic oxidation(PEO)coating on the magnesium(Mg)alloy,an inorganic salt combined with corrosion inhibitors was used for posttreatment of the coating.In this study,the corrosion performance of PEO-coated AM50 Mg was significantly improved by loading sodium lauryl sulfonate(SDS)and sodium dodecyl benzene sulf-onate into Ba(NO_(3))_(2) post-sealing solutions.Scanning electron microscopy,X-ray photoelectron spectroscopy,X-ray diffraction,Fourier transform infrared spectrometer,and ultraviolet-visible analyses showed that the inhibitors enhanced the incorporation of BaO_(2) into PEO coatings.Electrochemical impedance showed that post-sealing in Ba(NO_(3))_(2)/SDS treatment enhanced corrosion resistance by three orders of magnitude.The total impedance value remained at 926Ω·cm^(2)after immersing in a 0.5wt%NaCl solution for 768 h.A salt spray test for 40 days did not show any obvious region of corrosion,proving excellent post-sealing by Ba(NO_(3))_(2)/SDS treatment.The corrosion resistance of the coating was enhanced through the synergistic effect of BaO2 pore sealing and SDS adsorption.
出处 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第9期2048-2061,共14页 矿物冶金与材料学报(英文版)
基金 financial support by the National Natural Science Foundation of China(No.52071067) Shenyang Young and Middle-aged Science and Technology Innovation Talent Support Program,China(No.RC231178) Natural Science Foundation of Liaoning Province,China(No.2022-YGJC-16) the Fundamental Research Funds for the Central Universities,China(No.N2302019).
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