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Nickel-catalyzed arylcyanation of alkenes via cyano group translocation:access to 1,n-dinitriles or 4-amino nitriles

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摘要 Herein,a nickel-catalyzed arylcyanation of unactivated alkenes via cyano group translocation with aryl boronic acids has been developed.These transformations provided a robust approach to constructing structurally diverse 1,n-dinitriles or 4-amino nitriles from easily prepared and commercially available starting materials.The cyano group translocation was achieved,involving the addition into the intramolecular C–N triple bond followed by the retro-Thorpe reaction.Mechanistic studies revealed that high temperature and CsHCO_(3) as the base were crucial for the cyano group translocation.
出处 《Science China Chemistry》 SCIE EI CAS CSCD 2024年第9期2975-2981,共7页 中国科学(化学英文版)
基金 supported by the National Natural Science Foundation of China(21971074,22001076) the Natural Science Foundation of Guangdong Province(2022A1515010660,2021A1515220024) the Natural Science Foundation of Guangzhou(202102020982)。
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