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Synthesis of a New Type of Amphilic and Water - soluble Tertiary Phosphine Ligands Substituted by an Ethoxylated Phosphonic Acid Chain and Their Palladium Complexes

Synthesis of a New Type of Amphilic and Water - soluble Tertiary Phosphine Ligands Substituted by an Ethoxylated Phosphonic Acid Chain and Their Palladium Complexes
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摘要 The highly water-soluble phosphine ligands Na2O3PCH2CH2NH(CH2CH2O)nCH2CH2N- (CH2PPh2)2 (n=1,2,3) were prepared by a new and simple route under mild conditions in good yield; the palladium (II) complexes of the ligands 3a~c with 2:1 or 4:1 -PPh2 to Pd2+ molar ratio were also prepared and characterized . The highly water-soluble phosphine ligands Na2O3PCH2CH2NH(CH2CH2O)nCH2CH2N- (CH2PPh2)2 (n=1,2,3) were prepared by a new and simple route under mild conditions in good yield; the palladium (II) complexes of the ligands 3a^c with 2:1 or 4:1 -PPh2 to Pd2+ molar ratio were also prepared and characterized .
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 2002年第9期839-842,共4页 中国化学快报(英文版)
关键词 WATER-SOLUBLE diphenylphosphinomethyl phosphine ligands palladium complexes synthesis. Water-soluble diphenylphosphinomethyl phosphine ligands palladium complexes synthesis.
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