摘要
开发了一种Ag-Cu双金属负载的胺基石墨烯催化剂用于1,2,3-三唑类化合物的合成.利用各种技术对催化剂进行了表征,催化剂活性测试表明,该催化剂在温和反应条件下具有高催化活性、好的循环稳定性和易分离的特点.水作为绿色溶剂,反应收率高.该方法为β-羟基-1,2,3-三唑类化合物的水相绿色合成提供了一种可替代的多相催化策略,具有重要的科学价值.
An amino-functionalized graphene-immobilized Ag-Cu composite(Ag-Cu/GO-NH;)was synthesized.The properties of the prepared catalyst were analyzed using various techniques,that showed high catalytic activity,good recyclability,and easy separability in the green synthesis ofβ-hydroxy-1,2,3-triazole derivatives under mild reaction conditions resulting in good to excellent yields.It provided an alternative heterogeneous catalytic strategy for the green synthesis ofβ-hydroxy-1,2,3-triazoles in water,which had an important scientific significance.
作者
黄强
邓婷婷
朱佳运
李军
黎飞飞
Huang Qiang;Deng Tingting;Zhu Jiayun;Li Jun;Li Feifei(School of Pharmacy,Zunyi Medical University,Zunyi,Guizhou 563000;Key Laboratory of Basic Pharmacology of Ministry of Education,Zunyi Medical University,Zunyi,Guizhou 563000)
出处
《有机化学》
SCIE
CAS
CSCD
北大核心
2022年第2期534-542,共9页
Chinese Journal of Organic Chemistry
基金
遵义医科大学2018年学术新苗培养及创新探索专项(Nos.[2018]5772-013,CK-1149-011)
贵州省普通高等学校青年科技人才成长(No.KY[2021]221)资助项目
关键词
石墨烯
催化剂
1
2
3-三唑
点击化学
多相催化
graphene
catalyst
1,2,3-triazoles
click chemistry
heterogeneous catalysis